代表成果

车顺爱教授多年来从事多孔和手性无机材料的研究，在科研实践中积累了丰富的经验，取得了重要的研究成果。在世界高水平学术刊物上发表了多篇具有独创性和国际领先水平、并具有重要科学意义的学术论文, 对此领域做出了较突出的贡献：

(i)开辟了阴离子表面活性剂结构导向合成新型介孔材料的方法(Nature Mater. 2003, 2, 801; Chem. Soc. Rev. 2013, 42, 3740.); 

(ii)首次合成出手性介孔材料，提出了手性孔道概念(Nature, 2004, 429, 281.), 并证明了孔道中超分子螺旋印记的存在(Angew. Chem. Int. Ed., 2009, 48, 3069); 

(iii) 合成出具有二维四DNA-二氧化硅螺旋介观结构并解析了其形成机理 (Angew. Chem. Int. Ed., 2012, 51, 923); 

(iv)首次合成出螺旋TiO2，并提出基于电子跃迁引起的无机物光学活性概念(Nature Commun., 2013, 3, 1215,); 

(v)基于芳香基团的π-π作用导向合成了具有有序介孔结构的MFI型沸石材料(Nature Commun., 2014, 5, 4262)。

基于这些研究成果，车顺爱教授2008年被聘为瑞典斯德哥尔摩大学客座教授，2010年任国际介孔材料协会理事。 

研究领域

手性-多孔-介观无机材料的组装及其性能

微孔-介孔多级复合材料的合成及其性能

介孔，大孔材料的合成及其性能

专利

1. 后藤 康友、福岛 喜章、辰巳 敬、车 顺爱;Mesoporous Materials and their Synthesis Methods, Adsorbents and their Synthesis Methods;专利号：特许2002-022185.

2. 具有不同曲率的螺旋状金属或金属氧化物丝材料及其制备方法;专利号：2004100180212.

3. 具有手性结构的氧化硅介孔材料及其制备方法;专利号：2004100180208.

4. 车顺爱，吴小伟，靳海英 , 坂本一民;具有螺旋结构的氧化硅介孔材料的制备方法;专利号：2005100275838.

5. 车顺爱，于亚涛;具有均匀直径的介孔氧化硅管及其制备方法;专利号：200610119242.

6. 二木史朗，坂本一民，黒田一幸，寺崎治，车顺爱，后藤顺一;药物缓释二氧化硅;

7. 车顺爱,范茬兴;具有均匀、可调直径的手性介孔导电高分子的制备方法;专利号：200710047391.2.

8. 车顺爱，靳海英;一种二氧化硅介孔材料及其制备方法;专利号：200710046476.9.

9. 车顺爱，邱惠斌;一种氧化硅介孔晶体及其制备方法;专利号：200710042885.1.

10. 车顺爱，高传博，宫润欢;氧化硅介孔材料的制备方法;专利号：200910048733.1.

11. 车顺爱，金晨羽;二氧化硅介孔纤维的制备方法;专利号：200910049008.6.

12. 车顺爱，陈茜茹;单分散二氧化硅介孔球形材料的制备方法;专利号：200910195137.6.

13. 车顺爱，陈茜茹;二氧化硅介孔空心球形材料的制备方法;专利号：200910195138.0.

14. 车顺爱，郑浩铨，高传博，邢磊;基于配位键制备pH响应的药物释放系统;专利号：200910310620.4.

论文

1. Synthesis and Characterizationof Chiral Mesoporous Silica.S. Che,* Z. Liu, T. Ohsuna, K. Sakamoto, O. Terasaki and T. Tatsumi.Nature,2004.

2. Supramolecular Chiral Transcription and Recognition by Mesoporous Silica Prepared by Chiral Imprinting of a Helical Micelle.H. Qiu, Y. Inoue and S. Che*.Angew. Chem. Int. Ed.,2009.

3. Synthesis of Chiral TiO2 Nanofibre with Electron Transition-Based Optical Activity.S. Liu,† L. Han,† Y. Duan,† A. Shunsuke, O. Terasaki, Y. Cao, B. Liu, L. Ma, J. Zhang, S. Che*(†equal contribution).Nat. Commun.,2012.

4. Synthesis of Enantiopure Carbonaceous Nanotubes with Optical Activity.S. Liu, Y. Duan, X. Feng, J. Yang S. Che*.Angew. Chem. Int. Ed.,2013.

5. Optically Active Chiral CuO “Nanoflowers”.Y. Duan†, X. Liu†, L. Han†, S. Asahina, D. Xu, Y. Cao, Y. Yao, and S. Che*(†equal contribution).J. Am. Chem. Soc.,2014.

6. π–π Interaction of Aromatic Groups in Amphiphilic Molecules Directing for Single-Crystalline Mesostructured Zeolite Nanosheets.D. Xu†, Y. Ma†, Z. Jing†, L. Han, B. Singh, J. Feng, X. Shen, F. Cao, P. Oleynikov, H. Sun, O. Terasaki & S. Che*(†equal contribution).Nat. Commun.,2014.

7. A Novel Anionic Surfactant Templating Route for Synthesizing Mesoporous Silica with Unique Structure.S. Che,* A. E. Garcia-Bennett, T. Yokoi, K. Sakamoto, H. Kunieda, O. Terasaki and T. Tatsumi*.Nature Materials,2003.

8. Synthesis and Characterization of Mesoporous Silica AMS-10 with Bicontinuous Cubic Pn3m Symmetry.C. Gao, Y. Sakamoto,* K. Sakamoto, O. Terasaki and S. Che*.Angew. Chem. Int. Ed.,2006.

9. Evolution of Packing Parameter in Structural Changes of Silica Mesoporous Crystals: Cage–Type, 2D–Cylindrical, Bicontinuous Diamond and Gyroid, and Lamellar.L. Han, K. Miyasaka, O. Terasaki and S. Che*.J. Am. Chem. Soc.,2011.

10. Spontaneous Formation and Characterization of Silica Mesoporous Crystal Spheres with Reverse Multiply Twinned Polyhedral Hollows.L. Han, P. Xiong, J. Bai and S. Che*.J. Am. Chem. Soc.,2011.

11. Synthesis of a DNA–Silica Complex with a Rare Two–Dimensional–Square p4mm Symmetry.C. Jin†, L. Han† and S. Che* (†equal contribution).Angew. Chem. Int. Ed.,2009.

12. Formation of Enantiomeric Impeller-Like Helical Architectures by DNA Self-Assembly and Silica Mineralization.B. Liu†, L. Han† and S. Che* (†equal contribution).ngew. Chem. Int. Ed.,2012.

13. Template-Assisted Self-Assembly: Alignment, Placement, and Arrangement of Two-Dimensional Mesostructured DNA–Silica Platelets.B. Liu, Y. Yao and S. Che*.Angew. Chem. Int. Ed.,2013.

14. Recent progress in scanning electron microscopy for the characterization of fine structural details of nano materials.M. Suga*, S. Asahina, Y. Sakuda, H. Kazumori, H. Nishiyama, T. Nokuo, V. Alfredsson, T. Kjellman, S. M. Stevens, H. S. Cho, M. Cho, L. Han, S. Che, M. W. Anderson, F. Schüth, H. Deng, O. M. Yaghi, Z. Liu, H. Y. Jeong, A. Stein, K. Sakamoto, R. Ryoo, O. Terasaki**.Prog. Solid State Chem.,2014.

15. Silica Biomineralization via the Self-Assembly of Helical Biomolecules.B. Liu†, Y. Cao†, Z. Huang, Y. Duan and S. Che*(†equal contribution).Adv. Mater.,2015.

16. Coordination Bonding-Based pH-Responsive Drug Delivery Systems.H. Zheng, L. Xing, Y. Cao and S. Che*.Coord. Chem. Rev.,2013.

17. Anionic Surfactant Templated Mesoporous Silicas (AMSs).L. Han and S. Che*.Chem. Soc. Rev.,2013.

18. Carboxylic Group Functionalized Ordered Mesoporous Silicas.L. Han, O. Terasaki* and S. Che*.J. Mater. Chem.,2011.

19. Chiral Mesoporous Silica: Chiral Construction and Imprinting via Cooperative Self-Assembly of Amphiphiles and Silica Precursors.H. Qiu and S. Che*.Chem. Soc. Rev.,2011.

20. Organically Functionalized Mesoporous Silica by Co-structure-Directing Route.C. Gao and S. Che*.Adv. Funct. Mater.,2010.

21. An Appraisal of High-Resolution Scanning Electron Microscopy Applied to Porous Materials.S. M. Stevens, K. Jansson, C. Xiao, S. Asahina, M. Klingstedt, D. Grüner, Y. Sakamoto, K. Miyasaka, P. Cubillas, R. Brent, L. Han, S. Che, R. Ryoo, D. Zhao, M. Anderson, F. Schueth, and O. Terasaki*.JEOL News,2009.

22. Anionic Surfactant Templated Mesoporous Silica (AMS).C. Gao and S. Che*.Acta Petrolei Sinica.,2006.

23. Chiral Mesoporous Materials Based on the Self-Assembly.S. Che*.J. Nanosci. Nanotechnol.,2006.

24. Recent progress in scanning electron microscopy for the characterization of fine structural details of nano materials.M. Suga*, S. Asahina, Y. Sakuda, H. Kazumori, H. Nishiyama, T. Nokuo, V. Alfredsson, T. Kjellman, S. M. Stevens, H. S. Cho, M. Cho, L. Han, S. Che, M. W. Anderson, F. Schüth, H. Deng, O. M. Yaghi, Z. Liu, H. Y. Jeong, A. Stein, K. Sakamoto, R. Ryoo, O. Terasaki**.Prog. Solid State Chem.,2014.

25. Amphiphilic ABC triblock terpolymer templated large-pore mesoporous silicas.D. Xu, Z Huang, L. Han, Y. Yao,* S. Che*.Mater. Lett.,2015.

26. Silica Biomineralization via the Self-Assembly of Helical Biomolecules.B. Liu†, Y. Cao†, Z. Huang, Y. Duan and S. Che*(†equal contribution).Adv. Mater.,2015.

27. Synthesis of Single-Crystalline Mesoporous ZSM-5 with Three-Dimensional Pores via the Self-Assembly of a Designed Triply Branched Cationic Surfactant.B. Singh†, D Xu†, L. Han, J. Ding, Y. Wang, S. Che*(†equal contribution).Chem. Mater.,2014.

28. Synthesis and Characterization of Macroporous Photonic Structure that Consists of Azimuthally Shifted Double-Diamond Silica Frameworks.L. Han, D. Xu, Y. Liu, T. Ohsuna, Y. Yao, C. Jiang, Y. Mai, Y. Cao, Y. Duan and S. Che.Chem. Mater.,2014.

29. Molecular design of the amphiphilic AB diblock copolymer toward one-step synthesis of aminogroup functionalized large pore mesoporous silica†.D. Xu, Y. Yao,* L. Han and S. Che*.RSC Adv.,2014.

30. Control of Chiral Nanostructures by Self-Assembly of Designed Amphiphilic Peptides and Silica Biomineralization.Z. Huang, Y. Yao, L. Han and S. Che*.Chem. Eur. J.,2014.

31. Rigid bolaform surfactant templated mesoporous silicon nanofibers as anode materials for lithiumion batteries.D. Xu, Z. Huang, R. Miao, Y. Bie, J. Yang,* Y. Yao* and S. Che*.J. Mater. Chem. A,2014.

32. Structural roles of amphiphilic peptide tails on silica biomineralization.Z. Huang, H. Jin and S. Che*.Dalton Trans.,2014.

33. Surfactants with Aromatic-Group Tail and Single Quaternary Ammonium Head for Directing Single-Crystalline Mesostructured Zeolite Nanosheets.D. Xu, Z. Jing, F. Cao, H. Sun*, and S. Che*.Chem. Mater.,2014.

34. Optically Active Chiral CuO “Nanoflowers”.Y. Duan†, X. Liu†, L. Han†, S. Asahina, D. Xu, Y. Cao, Y. Yao, and S. Che*(†equal contribution).J. Am. Chem. Soc.,2014.

35. Growth of Optically Active Chiral Inorganic Films through DNA Self-Assembly and Silica Mineralisation.B. Liu, L. Han, Y. Duan, Y. Cao, J. Feng, Y. Yao & S. Che*.Scientific Reports,2014.

36. Design of Amphiphilic Peptide Geometry towards Biomimetic Self-Assembly of Chiral Mesoporous Silica.Z. Huang, Y. Yao and S. Che*.Chem. Eur. J.,2014.

37. An Insight into the Role of the Surfactant CTAB in the Formation of Microporous Molecular Sieves.D. Xu†, J. Feng† and S. Che*(†equal contribution).Dalton Trans.,2014.